Spain

Spain (スペイン) is a country located on the south-western coast of continental Europe, bordering Portugal and France.

Background
Since the sinking of the Spanish Armada, there has been some enmity between Spanish and English magic cabals. The Spanish Astrological Sect was mentioned as being the perpetrators of the "England Third Princess incident" ten years before the start of the series that Acqua of the Back is famous for stopping.

Spain is one of the increasing number of countries which have a space program.

Tree Diagram Remnant Arc
Spain was one of the countries that launched spacecraft to retrieve the remains of the destroyed Tree Diagram. Misaka 10854 reported that the launching spacecraft is happening in, Spain.

Toaru Majutsu no Index Light Novel Volume SS2
On the Second Friday of October, when the Sisters were dispatched to destroy the facilities of the Gemstone Mining research organizations around the world and rescue the gemstones imprisoned there, Misaka 19488 was sent to the Precise Micro Faith Association in Logroño, Spain. During her progress report, she mentioned that she had run into some assassins but had taken them out with a swift attack.